Product ID:TT-N-95, PETROLEUM NAPHTHA
MSDS Date:05/16/1991
FSC:6810
NIIN:00-082-1718
MSDS Number: BPQQR

SPECTRUM CHEMICAL MFG CORP

14422 S SAN PEDRO ST
GARDENA, CA 90248-2027
US

Emergency Phone: 213-516-8000

Info Phone: 213-516-8000

Cage: 63415

SPECTRUM LABORATORY PRODUCTS INC

GARDENA, CA 90248-2027 US

Telephone: 310-516-9843

Cage: 63415

NAPHTHALENE; (NAPHTHA) (SARA III)

CAS: 91-20-3

RTECS: QJ0525000

Fraction By Weight: 100%

OSHA PEL 10 PPM;15 PPM STEL

ACGIH TLV: 10 PPM;15 PPM STEL

EPA Report Quantity: 100 LBS

DOT Report Quantity: 100 LBS

BENZENE (SARA III)

CAS: 71-43-2

RTECS: CY1400000

Fraction By Weight: >0.1%

OSHA PEL 1 PPM;5 PPM STEL

ACGIH TLV: 10 PPM

EPA Report Quantity: 10 LBS

DOT Report Quantity: 10 LBS

ISOLATE FOR HALF MILE IN ALL DIRECTIONS IF TANK,

RTECS: 9999999ZZ

FLOW CAN BE STOPPED. SOLID STREAMS OF WATER MAY

RTECS: 9999999ZZ

MAY CAUSE

RTECS: 9999999ZZ

SENSATION, BUT ONLY SLIGHT, TRANSIENT CORNEAL INJURY

RTECS: 9999999ZZ

MEMBS, VOMIT & CNS DEPRESS. COUGH & CHOKING MAY

RTECS: 9999999ZZ

BURNING SENSATION IN MOUTH, THROAT & STOM, & HEMORR

RTECS: 9999999ZZ

LETHAL DOSE IN HUMANS IS 10-15 ML, BUT SMALLER AMTS

RTECS: 9999999ZZ

PRDCE LONGTERM EFTS W/PANCYTOPENIA PERSISTING UP TO

RTECS: 9999999ZZ

DEPRESS, MYOCARDIAL & HEMPTOPOIETIC EFTS &

RTECS: 9999999ZZ

REFERABLE TO CNS/HEMATOPOIETIC/IMMUNE SYS. RATS

RTECS: 9999999ZZ

MENSTRUAL DISTURBS HAVE BEEN REPORTED IN FREQ

RTECS: 9999999ZZ

SOME ANIMAL STUDIES HAVE DEMONSTRATED

RTECS: 9999999ZZ

ADMIN TO MICE SKIN RSLTD IN INCR INCIDENCE OF CARCIN

RTECS: 9999999ZZ

ERYTHEMIA, SCALING, DRYNESS, VESICULATION &

RTECS: 9999999ZZ

NEURITIS HAS ALSO BEEN REPORTED. SECONDARY

RTECS: 9999999ZZ

50% OF RATS EXPOS TO

RTECS: 9999999ZZ

ADMIN TO HUMANS OF 2-5 G CAUSED HDCH, VERTIGO,

RTECS: 9999999ZZ

EFTS HAVE BEEN REPORTED IN ANIMALS. FOR MORE

RTECS: 9999999ZZ

W/LG AMTS OF H*2O/NORM SALINE OCCAS LIFTING

RTECS: 9999999ZZ

EXTREME

RTECS: 9999999ZZ

ENDOTRACHEAL TUBE SHLD BE DONE W/IN 15 MINS. IN

RTECS: 9999999ZZ

BE INDUCED USING SYRUP OF IPECAC W/OUT INCR ASPIR

RTECS: 9999999ZZ

SMOKING/FLAMES/FLARES IN HAZARD AREA. ISOLATE

RTECS: 9999999ZZ

LD50 LC50 Mixture:LD50:(ORAL,RAT)930 MG/KG.
Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO
Health Hazards Acute and Chronic:ACUTE:ING 1:INHAL:VAPS MAY CAUSE IRRIT
OF NOSE & THROAT & LOWER RESP TRACT. IN MASSIVE EXPOS, RAPID CNS
DEPRESS MAY OCCUR W/SUDDEN COLLAPSE, UNCON, COMA & DEATH. THERE MAY
BE CONVLS & VISCERAL DMG. IN G 2:MAY CAUSE RESP TRACT IRRIT; MORE
SEV EXPOS MAY RSLT IN PULM EDEMA. SYSTEMIC EFTS ARE MAINLY ON
CNS.(EFTS OF OVEREXP)
Explanation of Carcinogenicity:BENZENE:IARC GRP 1, NTP KNOWN
CARCINOGEN, OSHA REGULATED.
Effects of Overexposure:HLTH HAZ:LIVER & KIDNEY EFTS MAY OCCUR.
CHROMOSOMAL DMG HAS BEEN FOUND. DEATH MAY BE DUE TO ASPHYXIA, CNS
DEPRESS, CARDIAC/RESP FAILURE OR CIRCULATORY COLLAPSE. SKIN:ING
1:SLIGHT TO SEV IRRRIT; PRLNG CONT MAY RSLT IN ERYTHEMA,
BLISTERING &BURNS. ING 2:MAY CAUSE IRRIT. EYE:ING 1:VAP MAY CAUSE
IRRIT; SPLASHES MAY(ING 5)
Medical Cond Aggravated by Exposure:ING 1:PERSONS W/CHRONIC
SKIN/RESPIRATORY DISEASE. ING 2:PERSONS W/CERTAIN IMMUNOLOGICAL
TENDENCIES, POOR NUTRITION, ANEMIA & DRUG/CHEMICALLY INDUCED
AGRANULOCYTOSIS.

First Aid:INHAL:REMOVE TO FRESH AIR IMMED. IF BRTHG HAS STOPPED, GIVE
ARTF RESP. MAINT AIRWAY & BLOOD PRESS & ADMIN O*2 IF AVAIL. KEEP
PERS WARM & @ REST. ADMIN OF O*2 SHLD BE PERFORMED BY QUALIFIED MED
PERS. G ET MD IMMED. SKIN:REMOVE CONTAM CLTHG &SHOES IMMED. WASH
AFFECTED AREA W/SOAP/MILD DETERGENT & LG AMTS OF H*2O UNTIL NO EVID
OF CHEM REMAINS (APPROX 15-20 MINS). GET MD IMMED. EYE:WASH IMMED
(ING 21)

Flash Point:>-40F,>-40C
Lower Limits:1%
Upper Limits:6%
Extinguishing Media:DRY CHEMICAL, CO*2, WATER SPRAY/ALCOHOL-RESISTANT
FOAM. FOR LARGER FIRES, USE WATER SPRAY, FOG/ALCOHOL-RESISTANT
FOAM.
Fire Fighting Procedures:WEAR NIOSH/MSHA APPRVD SCBA & FULL PROT EQUIP
. MOVE CNTNR FROM FIRE AREA IF YOU CAN DO IT W/OUT RISK. APPLY
COOLING H*2O TO SIDES OF CNTNRS THAT (SUPDAT)
Unusual Fire/Explosion Hazard:DANGEROUS FIRE HAZ WHEN EXPOSED TO
HEAT/FLAME. VAP-AIR MIXTS ARE EXPLO >FL PT. VAPS ARE HVR/AIR & MAY
TRAVEL CONSIDERABLE DIST TO SOURCE OF IGNIT & FLASH BACK.

Spill Release Procedures:SHUT OFF IGNIT SOURCES. STOP LEAK IF YOU CAN
DO IT W/OUT RISK. USE H*2O SPRAY TO REDUCE VAPS. FOR SM SPILLS,
TAKE UP W/SAND/OTHER ABSORB MATL & PLACE INTO CNTNRS FOR LATER
DISP. FOR LGR SPILLS, DIKE F AR AHEAD OF SPILL FOR LATER DISP. NO
(ING 25)
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:STORE I/A/W 29CFR1910.106. OBSERVE ALL
FED, STATE & LOC REGS WHEN STORING THIS SUBSTANCE. FOR ASSISTANCE,
CONT DISTRICT DIRECTOR OF EPA.
Other Precautions:BONDING & GROUNDING:SUBSTANCES W/LOW
ELECTROCONDUCTIVITY, WHICH MAY BE IGNITED BY ELECTROSTATIC SPKS,
SHLD BE STORED IN CNTNRS WHICH MEET GUIDELINES SPECIFIED IN NFPA.
STORE AWAY FROM INCOMPAT SUBSTAN CES.

Respiratory Protection:SPECIFIC RESPIRATOR SELECTED MUST BE BASED ON
CONTAM LEVELS FOUND IN WORK PLACE, MUST NOT EXCEED WORKING LIMITS
OF RESPIRATOR & BE NIOSH/MSHA APPROVED. FOR SPECIFIC RESPIRATOR
SELECITON, CONTACT NEHC .
Ventilation:PROVIDE LOCAL EXHAUST VENTILATION TO MEET PELS. VENTILATION
EQUIPMENT MUST BE EXPLOSION-PROOF.
Protective Gloves:IMPERVIOUS GLOVES .
Eye Protection:CHEMICAL WORKERS GOGGLES .
Other Protective Equipment:APPROP PROT (IMPERVIOUS) CLTHG & EQUIP.
PROVIDE EYE WASH FOUNTAIN W/IN IMMED WORK AREA FOR EMEGENCY USE.
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
FIRE FIGHT:ARE EXPOSED TO FLAMES UNTIL WELL AFTER FIRE IS OUT. STAY
AWAY FROM ENDS OF TANKS. FOR MASSIVE FIRES IN CARGO AREA, USE
UNMANNED HOSE HOLDER/MONITOR NOZZ; IF IMPOSS, W/DRAW FROM AREA &
LET F IRE BURN. W/DRAW IMMED IN CASE OF RISING SOUND FROM VENTING
SFTY DEVICE/ANY DISCOLORATION OF TANK DUE TO FIRE. (ING 3)

Boiling Pt:B.P. Text:>86F,>30C
Melt/Freeze Pt:M.P/F.P Text:-70F,-57C
Vapor Pres:40 @ 20C
Vapor Density:3.4
Spec Gravity:0.74
Evaporation Rate & Reference:10 (BUTYL ACETATE = 1)
Solubility in Water:0.04%
Appearance and Odor:COLORLESS LIQUID W/ODOR LIKE GASOLINE OR KEROSENE.

Stability Indicator/Materials to Avoid:YES
STRONG OXIDANTS.
Stability Condition to Avoid:AVOID CONT W/HEAT, SPKS, FLAMES/OTHER
SOURCES OF IGNIT. VAPS MAY BE EXPLO. AVOID OVERHEATING OF CNTNRS.
Hazardous Decomposition Products:THERMAL DECOMPOSITION PRODUCTS MAY
INCLUDE TOXIC CO*X.

Waste Disposal Methods:DISP MUST BE I/A/W STDS APPLIC TO GENERATORS OF
HAZ WASTE, 40CFR262. EPA HAZ WASTE NO:D001. ING 2:EPA HAZ WASTE
NO:D018. OBSERVE ALL FED, STATE & LOC REGS WHEN DISP OF THIS
SUBSTANCE. FOR ASSISTANCE, CONT DISTRICT DIRECTOR OF EPA.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.